Cover Feature: Structural Diversity and Argentophilic Interactions in Small Phosphine Silver(I) Thiolate Clusters (Eur. J. Inorg. Chem. 27/2021)

The Cover Feature shows the Ag⋅⋅⋅Ag interactions in various small phosphine silver(I) thiolate clusters. argentophilic contacts can be either attractive or repulsive as a function of electronic and geometric environment silver centers, which is turn modulated by ligand effects. real space electron density (QTAIM NCI-index) energy decomposition (IQA) analyses deliver insights into these Our investigation provides new tools for precise atomic design construction higher nuclearity background was adapted from image Crab Nebula Taurus (Credit: ESO). More information found Full Paper G. Moreno-Alcántar co-workers.